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tungsten trioxide : ウィキペディア英語版
tungsten trioxide

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Tungsten(VI) oxide, also known as tungsten trioxide or tungstic anhydride, WO3, is a chemical compound containing oxygen and the transition metal tungsten. It is obtained as an intermediate in the recovery of tungsten from its minerals. Tungsten ores are treated with alkalis to produce WO3. Further reaction with carbon or hydrogen gas reduces tungsten trioxide to the pure metal.
:2 WO3 + 3 C → 2 W + 3 CO2 (high temperature)
:WO3 + 3 H2 → W + 3 H2O (550 - 850 °C)
Tungsten(VI) oxide occurs naturally in form of hydrates, which include minerals: tungstite WO3·H2O, meymacite WO3·2H2O and hydrotungstite (of same composition as meymacite, however sometimes written as H2WO4). These minerals are rare to very rare secondary tungsten minerals.
==History==
Tungsten has a rich history dating back to its discovery during the 18th century. Peter Woulfe was the first to recognize a new element in the naturally occurring mineral wolframite. Tungsten was originally known as wolfram, explaining the choice of "W" for its elemental symbol. Swedish chemist Carl Wilhelm Scheele contributed to its discovery as well with his studies on the mineral scheelite.〔
In 1841, a chemist named Robert Oxland gave the first procedures for preparing tungsten trioxide and sodium tungstate. He was granted patents for his work soon after, and is considered to be the founder of systematic tungsten chemistry.〔

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